Total amount control is an important environmental protection policy. It is difficult for us to get a comprehensive assessment of it, because of the complexity of the influencing factors. In this study, a multi-level grey comprehensive evaluation method was established for total mount control of water pollutants by using grey relational analysis. The total amount levels of 27 provinces were calculated with this method. Those levels can more comprehensively reflect the situation of water pollution control in provinces than single-factor evaluation.